Spherical Transition Moment

This transition moment can be used for any molecule type, and must be used for multiphoton or Raman transitions. It is also appropriate for single photon transitions classified as parallel or perpendicular, as noted below.

Settings

RankRank of transition - 2 (twice 1) for a normal electric dipole transition.
ComponentProjection quantum number of transition moment - 0 for a parallel transition, 2 (twice 1) for a perpendicular transition.

Parameters

StrengthTransition (dipole) moment. For one photon transitions this has units of Debye. Note that the relative intensity is proportional to the square of this value.
CJ dependence of transition moment
DJ dependence of transition moment