Line Intensity Fitting
Line intensities can also be fit, which makes sense in three
The essential procedure is the same as for line position fitting,
except that the line intensities replace the positions in the
observations file. When fitting, the Fit type combo box should be set to "Intensity"
rather than "Line", and you will want to make sure that only
parameters affecting the intensity are floated. (In principle this
will be all parameters, but you will normally want to float the
transition moments and temperature only.)
- Where absolute intensities have been measured and a fit can
therefore determine the transition moment.
- Relative intensities have been measured of two or more bands,
and the relative transition moments are required.
- A series of relative intensity measurements have been made,
and the population distribution are required.
To fit populations set the required levels up as described in Non-Boltzmann Populations; this then
provides a parameter for each level of interest in the manifold that
can be floated as for other parameters. Again you will normally want
to float these population parameters only.
Energy Level fits
This is essentially a special case of a line position fit. To force
the observed value in a given line in the input file to be treated
as an energy level, rather than a transition frequency, replace J S and #
for the unwanted state with "-" and leave the manifold field blank.
It is also possible to force this for a complete file from the Log Window. If HITRAN or JPL line catalog
files are used as input, then these have energy level information in
them and selecting EUpper or ELower in the log
window will cause the state energy to be worked out (using the line
position and lowers state energy for EUpper). For other
file formats the values given in the file must be the energy level.